Basically, the only thing that the two sets have in common is that they both have planes. However there is quite a bit of difference on the inside of the planes. There are a lot more details in the Friends plane. In addition to the seats, there is a rolling service cart complete with refreshments, emergency lighting as well as a larger galley and lav in the back of the plane.
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If you don’t own Black Panther Pursuit or any of the sets that included Captain America, I guess it would a plus getting the both of them in this set but Super Heroes collectors tend to be completionists, so I think that scenario will be particularly rare. I guess you could always sell your spares on the secondary market, but really, who wants to do that?

City is the thematic title under which most Town-related System sets were released from 2005 and onward. There are numerous sets that are associated with Construction, Police, Fire, Emergency, Train, Airport, Transportation, Cargo, Traffic, Coast Guard, Farm, Great Vehicles, Mining, and Space. European catalogs featured another theme called City in the years 1999 to 2000, which was referred to as City Center in American catalogs.
The box set weighs a little over 2kg and has about 694 pieces in total, including 6 minifigures: a pilot, 3 airport workers, a male and a female passenger. The whole build would get you almost an entire airport facade with a pretty big passenger plane, an airport/control tower build, and an airport service car that tows with it a luggage, fuel and and mobile stairway.
The final two minifigures are the Biplane Pilot and the intrepid Wing Walker. Both of these minifigures share the same white torso which is printed with a flight suit design overlaid with dark red and bright light orange flames plus a logo over the left breast. The torso design is superb and it can at present only be found in this set. Both minifigures are provided with a reddish brown aviator cap and dark bluish grey goggles, and the pilot (below left) also gets an alternative to this headgear in the form of medium dark flesh mid-length hair which has only ever appeared in five sets in this colour.
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